ZnO-Activated Carbon Blended as a Catalyst for Oxidative Desulfurization of Dibenzothiophene
نویسندگان
چکیده
The problem of sulfur content in heavy oil is a challenge for researchers to meet the needs environmentally friendly fuels. catalyst preparation plays an important role desulfurization process. synthesis ZnO-activated carbon as and its activity oxidative (ODS) reaction has been successfully carried out. In this work, ZnO activated (AC) were blended by solid-solid reaction. ZnO, AC, ZnO-AC then characterized using acidity test with pyridine vapor adsorption, Fourier Transform Infra-Red (FTIR), X-ray Diffraction (XRD), Scanning Electron Microscope-Energy Dispersive X-Ray (SEM-EDX), Surface Area Analyzer (SAA). ODS dibenzothiophene (DBT) was performed H2O2 under variation time (30, 60, 120, 150 min) catalyst. efficiency ODS-DBT analyzed UV-Visible spectrophotometer. XRD analysis result showed that displays new crystal peaks Zn AC diffractogram. surface area (734.351 m2/g) (4.8780 mmol/g) higher than themselves. produced highest which 93.83% 120 min. Therefore, simple procedure physical blending proved effective homogenize between into so it good physicochemical properties Copyright © 2021 Authors, Published BCREC Group. This open access article CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
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چکیده ندارد.
Oxidative desulfurization of dibenzothiophene with molecular oxygen using emulsion catalysis.
Dibenzothiophene (DBT) is oxidized to the corresponding sulfoxide and sulfone in an emulsion system (W/O) composed of polyoxometalate anion [C(18)H(37)N(CH(3))3](5)[PV(2)Mo(10)O(40)] as both the surfactant and catalyst, using molecular oxygen as the oxidant and aldehyde as the sacrificial agent under mild conditions.
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ژورنال
عنوان ژورنال: Bulletin of Chemical Reaction Engineering & Catalysis
سال: 2021
ISSN: ['1978-2993']
DOI: https://doi.org/10.9767/bcrec.16.4.11797.881-887